​290. Catalytic Cascade Dehydrogenative Cross-Coupling of BH/CH and BH/NH: One-Pot Process to Carborano-Isoquinolinone
Au, Y. K.; Lyu, H.; Quan, Y.; Xie, Z.
J. Am. Chem. Soc. 2019, 141, 12855-12862. 
289. How long a C–C bond can be? An example of extraordinary long C–C single bond in 1,2-diarylamino-o-carborane
Wu, Y.; Zhang, J.; Xie, Z.
Chin. Chem. Lett. 2019, 30, 1530-1532.
288. Catalytic Regioselective Cage B(8)–H Arylation of o-Carboranes via “Cage-Walking” Strategy
​Lyu, H.; Zhang, J.; Yang, J.; Quan, Y.; Xie, Z.
J. Am. Chem. Soc. 2019, 141, 4219-4224.
287. ​Controlled functionalization of o-carborane viatransition metal catalyzed B–H activation
​Quan, Y.; Xie, Z.
Chem. Soc. Rev. 2019, 48, 3660-3673.
286. ​Nucleophilic substitution: a facile strategy for selective B–H functionalization of carboranes
​Quan, Y.; Tang, C.; Xie, Z.
Dalton Trans. 2019, 48, 7494-7498.

285. ​Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranes
Chen, Y.; Au, Y. K.; Quan, Y.; Xie, Z.
Sci. China Chem., 2019, 62, 74-79.

284. ​Regioselective Nucleophilic Alkylation/Arylation of B–H Bonds in o-Carboranes: An Alternative Method for Selective Cage Boron Functionalization
​Tang, C.; Zhang, J.; Zhang, J.; Xie, Z.
J. Am. Chem. Soc., 2018, 140, 16423-16427.

283. ​Broad Scope Extra‐Annular [4 + 2] Cycloaddition of o‐Carboryne with Styrenes: Efficient Route to Carborane‐Fused Polycyclics
Zhang, J.; Xie, Z.
​Chin. J. Chem. 2018, 36, 1041-1046.

282. Rhodium catalyzed cascade cyclization featuring B–H and C–H activation: one-step construction of carborane-fused N-polyheterocycles
Lyu, H.; Quan, Y.; Xie, Z.
Chem. Sci., 2018, 9, 6390-6394

281. Reaction of o‐Carboryne with Furans: Facile Synthesis of Carborane-Fused Oxanorbornenes and Their Derivatives
Zhang, R.; Yuan, Y.; Qiu, Z.; Xie, Z.
Chin. J. Chem. 2018, 36, 273-279.

280. 16th International Meeting on Boron Chemistry (IMEBORON XVI)
Xie, Z.
Pure Appl. Chem. 2018, 90, 605.
279. Enantioselective Synthesis of Chiral-at-Cage o-Carboranes via Pd-Catalyzed Asymmetric B–H Substitution
Cheng, R.; Li, B.; Wu, J.; Zhang, J.; Qiu, Z.; Tang, W.; You, S. L.; Tang, Y.; Xie, Z.
J. Am. Chem. Soc. 2018, 140, 4508-4511.

278. Transition‐Metal‐Like Behavior of Monovalent Boron Compounds: Reduction, Migration, and Complete Cleavage of CO at a Boron Center
Wang, H.; Wu, L.; Lin, Z.; Xie, Z.
​​Angew. Chem. Int. Ed. 2018, 57, 8708-8713.

277. Borylene Insertion into Cage B–H Bond: A Route to Electron-Precise B–B Single Bond
Wang, H.; Zhang, J.; Lee, H. K.; Xie, Z.
J. Am. Chem. Soc. 2018, 140, 3888-3891.
276. Synthesis, structure and reactivity of a carborane-fused silylene 1-{[PhC(NtBu)2]Si}-1,2-C2B10H11
Wang, H.; Zhang, J.; Xie, Z.
​​J. Organomet. Chem. 2018, 865, 173-177.
275. ​Transition‐Metal‐Catalyzed Selective Cage B−H Functionalization of o‐Carboranes
Quan, Y.; Qiu, Z.; Xie, Z.
Chem. Eur. J. 2018, 24, 2795-2805.
274. Cage carbon-substitute does matter for aggregation-induced emission features of o-carborane-functionalized anthracene triads
Wu, X.; Guo, J.; Quan, Y.; Jia, W.; Jia, D.; Chen, Y.; Xie, Z.
J. Mater. Chem. C 2018, 15, 4140-4149.
273. Synthesis of carborane-fused carbo- and heterocycles via zirconacyclopentane intermediates
Cui, C. X.; Ren, S.; Qiu, Z.; Xie, Z.
Dalton Trans. 2018, 47, 2453-2459.
272. Synthesis, structure and aromaticity of carborane-fused carbo- and heterocycles
Chan, T. L.; Xie, Z.
Chem. Sci. 2018, 9, 2284-2289.
271. Cyclic amino(carboranyl) silylene: synthesis, structure and reactivity
Wang, H.; Chan, T. L.; Xie, Z.
Chem. Commun. 2018, 54, 385-388.

270. Broad Scope [4 + 2] Cycloaddition of o-Carboryne with Pentafulvenes Using 1-Li-2-OTf-o-C2B10H10 as Precursor
Zhang, J.; Qiu Z.; Xie, Z.
​Organometallics 2017, 36, 3806-3811.

269. Synthesis, Structure and Reactivity of a Borylene Cation [(NHSi)2B(CO)]+ Stabilized by Three Neutral Ligands
Wang, H.; Wu, L.; Lin, Z.; Xie, Z.
​J. Am. Chem. Soc. 2017, 139, 13680-13683.
268. Transition Metal Catalyzed Regioselective B (4)‐Halogenation and B (4, 5)‐Diiodination of Cage B‐H Bonds in o‐Carboranes
Lyu, H.; Quan, Y.; Xie, Z.
Chem. Eur. J. 2017, 23, 14866-14871.
267. Reversible Photothermal Isomerization of Carborane-Fused Azaborole to Borirane: Synthesis and Reactivity of Carbene-Stabilized Carborane-Fused Borirane
Wang, H.; Zhang, J.; Xie, Z.
​Angew. Chem. Int. Ed. 2017, 56, 9198-9201.
266. Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4-Alkylation of o-Carboranes​
Tang, C.; Zhang, J.; Xie, Z.
​Angew. Chem. Int. Ed. 2017, 56, 8642-8646. 
265. Iridium-catalysed regioselective borylation of carboranes via direct B-H activation
Cheng, R.; Qiu, Z.; Xie, Z.
Nat Commun. 2017, 8, 14827.
264. Reactivity of mixed-sandwich zirconacarborane alkyls with polar unsaturated molecules
Liu, D.; Qiu, Z.; Xie, Z.
​J. Organomet. Chem. 2017, 847, 97-104.
263. Dehydrogenative cross-coupling of o-carborane with thiophenes via Ir-catalyzed regioselective cage B–H and C (sp2)–H activation
Quan, Y.; Lyu, H.; Xie, Z.
Chem. Commun. 2017, 53, 4818-4821.
262. Cycloheptatrienyl dicarbollyl zirconium complexes: Building blocks for the preparation of multidecker sandwich complexes
Bannenberg, T.; Glöckner, A.; Lemke, M.; Yang, J.; Xie, Z.; Tamm, M.; Jones, P. G.
J. Organomet. Chem. 2017, 828, 83-88.
261. Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]n-o-Carboranes (n = 1,2) and o-Carborane-Fused Cyclics
Ni, H.; Qiu, Z.; Xie, Z.
​Angew. Chem. Int. Ed. 2017, 56, 712-716. 

260. Enantioselective Construction of Cyclobutanes: A New and Concise Approach to the Total Synthesis of (+)-Piperarborenine B
Hu, J.-L.; Feng, L-W.; Wang, L.; Xie, Z.; Tang, Y.; Li, X.
J. Am. Chem. Soc. 2016, 138, 13151-13154.

259. Transition Metal Catalyzed Direct Amination of Cage B(4)−H Bond in o-Carboranes: Synthesis of Tertiary, Secondary and Primary o-Carboranyl Amines
Lyu, H.; Quan, Y.; Xie, Z.
J. Am. Chem. Soc. 2016, 138, 12727-12730.
258. Rh-Catalyzed Regioselective Cage B-H Hydroxylation of o-Carboranes with O2 or Air
Lyu, H.; Quan, Y.; Xie, Z.
Angew. Chem. Int. Ed. 2016, 55, 11840-11844.

257. Unique properties of C,C′-linked nido-biscarborane tetraanions. Synthesis, structure and bonding of ruthenium monocarbollide via unprecedented cage carbon extrusion
Zhao, D.; Zhang, J.; Lin, Z.; Xie, Z.
​Chem. Commun. 2016, 52, 9992-9995.

256. Phosphine-catalyzed cage carbon functionalization of o-carborane: facile synthesis of alkenylcarboranes
Zheng, F.; Leung, T. F.; Chan, K. W.; Sung H. H. Y.; William, I. D. ; Xie, Z.; Jia, G.
Chem. Commun. 2016, 52, 10767-10770.

255. Synthesis and Structural Characterization of Carbene-Stabilized Carborane-Fused Azaborolyl Radical Cation and Dicarbollyl-Fused Azaborole
Wang, H.; Zhang, J.; Lin, Z.; Xie, Z.
Organometallics 2016, 35, 2579-2582.

254. Synthesis, structure and reactivity of mixed-sandwich zirconacarborane methyl complex (η5-C5Me5)[η1: η5-(R2NCH2CH2)C2B9H10]ZrMe
Liu, D.; Qiu, Z.; Xie, Z.
J. Organomet. Chem. 2016, 822, 144-153.

253. Palladium catalyzed regioselective B–C (sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranes
​Quan, Y.; Tang, C.; Xie, Z.
Chem. Sci. 2016, 7, 5838-5845.​​

252. [3-N2-o-C2B10H11][BF4]: A Useful Synthon for Multiple Cage Boron Functionalization of o-Carborane
​Zhao, D.; Xie, Z.
Chem. Sci. 2016, 7, 5635-5639.​​
251. The synthesis, structure and reactivity of an imine-stabilized carboranylphosphorus(I) compound
​Chan, T. L.; Xie, Z.
Chem. Commun. 2016, 52, 7280-7283.
​250. Reaction of [η1: η5-(R2NCH2CH2) C2B9H10] TaMe3 with Isonitriles: Effects of Nitrogen Substituents on Product Formation
​Xiang, L.; Xie, Z.
Organometallics, 2016, 35, 1430-1439.
249. Visible-Light-Promoted Photocatalytic B−C Coupling via a Boron-Centered Carboranyl Radical: Facile Synthesis of B(3)-Arylated o-Carboranes
​Zhao, D.; Xie, Z.
Angew. Chem. Int. Ed., 2016, 55, 3166-3170.
248. Tantallacarborane Mediated Consecutive C–C and C–N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N-Heterocycles
Xiang, L.; Xie, Z.
Organometallics 2016, 35, 233-241.
247. Facile Synthesis of N-Carboranyl Amines through an ortho-Carboryne Intermediate
Cheng, R.; Zhang, J.; Zhang, J.; Qiu, Z.; Xie, Z.
Angew. Chem. Int. Ed. 2016, 55, 1751-1754.
245. Palladium-catalyzed regioselective diarylation of o-carboranes by direct cage B-H activation​
Quan, Y.;  Xie, Z.
Angew. Chem. Int. Ed., 2016, 55, 1295-1298.
245. Recent Advances in the Chemistry of Carborynes
Zhao, D.; Xie, Z.
​Coord. Chem. Rev. 2016, 314, 14-33.
244. DFT Studies on Structures, Stabilities, and Electron Affinities of closo-Supercarboranes C2Bn–2Hn (n = 13–20)
Zhang, J; Lin, Z.; Xie, Z.
Organometallics 2015, 34, 5576-5588.
243. The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound
​Wang, H.; Zhang, J.; Lin, Z.; Xie, Z.
Chem. Commun. 2015, 51, 16817-16820.
242. An unprecedented Formal [5 + 2] Cycloaddition of Nitrones with o-Carboryne via Tandem [3 + 2] Cycloaddition/Oxygen Migration/Aromatization Sequence
Zhao, D.; Zhang, J.; Xie, Z.
J. Am. Chem. Soc. 2015, 137, 13938-13942.
241. Palladium-Catalyzed Direct Dialkenylation of Cage BH Bonds in o-Carboranes through Cross-Coupling Reactions
Lyu, H.; Quan, Y.;  Xie, Z.
Angew. Chem. Int. Ed., 2015, 54, 10623-10626.
240. Asymmetric Hydroamination Catalyzed by A New Chiral Zirconium System: Reaction Scope and  Mechanism
Zhou, X.; Wei, B.; Sun, X.-L.; Tang, Y.; Xie, Z.
Chem. Commun. 2015, 51, 5751-5753.
239. Dearomative [2 + 2] Cycloaddition and Formal C-H Insertion Reaction of o-Carboryne with Indoles: Synthesis of Carborane-Functionalized Heterocycles
Zhao, D.; Zhang, J.; Xie, Z.
J. Am. Chem. Soc. 2015, 137, 9423-9428.
238. Facile Synthesis of o-Carborane-Substituted Alkenes and Allenes by a Regioselective Ene Reaction of 1,3-Dehydro-o-carborane
Zhao, D.; Zhang, J.; Xie, Z.
Chemistry—A European Journal. 2015, 21, 10334-10337.
237. Highly Diastereoselective and Enantioselective Formal [4 + 3] Cycloaddition of Donor-acceptor Cyclobutanes with Nitrones
Hu, J.-L.; Wang, L.; Xu, H.; Tang, Y.; Xie, Z.
Org. Lett., 2015, 17, 2680–2683.
236. Nickel-Catalyzed Cross-Coupling Reactions of o-Carboranyl with Aryl Iodides: Facile Synthesis of 1-Aryl-o-Carboranes and 1,2-Diaryl-o-Carboranes
Tang, C.; Xie, Z.
Angew. Chem. Int. Ed., 2015, 54, 7662-7665.
235. o-Carborane Functionalized Pentacenes: Synthesis, Molecular Packing and Ambipolar Organic Thin film Transistors
Guo, J.; Liu, D.; Zhang, J,; Zhang, J,; Miao, Q.; Xie, Z.
Chem. Commun. 2015, 51, 12004-12007.
234. Palladium-Catalyzed Regioselective Intramolecular Coupling of o-Carborane with Aromatics via Direct Cage B-H Activation
Quan, Y.; Qiu, Z.; Xie, Z. 
J. Am. Chem. Soc. 2015, 137, 3502–3503.
233. Reaction of N-heterocyclic Carbenes with 13-Vertex Closo-carboranes: Synthesis and Structural Characterization of Zwitterionic Salts of 13-Vertex Nido-carboranes
Zheng, F.; Xie, Z. 
Org. Chem. Front., 2015, 2, 55-59.
232. Reactivity of Traditional Metal-Carbon (Alkyl) versus Nontraditional Metal-Carbon (Cage) Bonds in Organo-Rare-Earth Metal Complexes [η5:σ-(C9H6)(C2B10H10)]Ln(CH2C6H4-o-NMe2)(THF)2
Yang, J; Xie, Z.
Organometallics 2015, 34, 2494-2499.
231. Supercarborane Radical Anions with 2n + 3 Electron Counts: A Combined Experimental and Theoretical Study
Zhang, J; Fu, X.; Lin, Z.; Xie, Z.
Inorg. Chem. 2015, 54, 1965-1973.
230. Synthesis, Structure and Reactivity of Highly Constrained-geometry Yttracarborane Alkyl [σ:η5-(C9H6)C2B9H10]Y[η2-(CH3OCH2CH2OCH3)]2
Yang, J; Shen, H.; Xie, Z.
J. Organomet. Chem. 2015, 798, 204-208.
229. Synthesis, structure and reactivity of rare-earth metallacarborane alkyls [η1:η5-O(CH2)2C2B9H9]Ln(σ:η1-CH2C6H4-o-NMe2)(THF)2
Yang, J; Xie, Z.
Dalton Trans. 2015, 44, 6630-6637.
228. Synthesis, Structure, and Alkyne Insertion of a Mixed-sandwich Zirconacarborane Alkyl
Liu, D; Qiu, Z.; Xie, Z.
Inorg. Chem. Front., 2015, 2, 467-472.